STUDY OF THE INFLUENCE OF COMPOUNDS OF THE ANO3 and ANO3 nH2O TYPES ON RHEOKINETIC AND COLLOID-CHEMICAL PROPERTIES OF ALUMINOSILICATE ADHESIVES FOR WOOD
Abstract
In the technology of gluing solid wood, various adhesives are used, which, in addition to ensuring the strength of the gluing, must also be characterized by a number of rheological and colloidal-chemical properties, namely: have acceptable viscosity, low contact angles, have good spreading and enveloping ability, penetrate deep into the wood , providing reliable cohesive-adhesive contact and much more. Today, adhesives based on PVA dispersions and urea formaldehydes are used, the properties of which have been sufficiently studied and tested in practice. An alternative to organic-based adhesives is mineral adhesives, in particular aluminosilicate adhesives, which are non-flammable and have high mechanical strength.
Object of research: rheokinetic patterns and processes of formation of colloidal-chemical structures of aluminosilicate adhesives modified with compounds of the ANO3 and ANO3×nH2O type.
Investigated problem: Considering that aluminosilicate adhesives are multiphase reactive suspensions, the viscosity of which changes over time and affects their viability, the issue of viscosity stabilization due to the introduction of electrolyte salts into their composition is relevant, and will also contribute to improving the wettability and spreading of the adhesive during applying them to substrates and gluing samples from various types of wood.
Main scientific results: The effect of the concentrations of compounds of the ANO3 and ANO3×nH2O type on the rheokinetic and chemical-colloidal properties of the aluminosilicate adhesive has been established, which will make it possible to use aluminosilicate adhesives in practice for gluing wood of various species, as well as to work out possible technological methods of their application, taking into account the obtained data on the viscosity, wetting and spreadability of the modified adhesive on the surface of the wood substrate.
Area of practical use of the research results: woodworking enterprises for the production of glued solid wood products.
Innovative technological product: aluminosilicate adhesives modified with ANO3 and ANO3×nH2O nitrate additives for gluing wood of various species.
Scope of application of an innovative technological product: the application of these approaches will make it possible to obtain glued materials from wood from different species with improved technological and physical and mechanical properties of the glue seam and, accordingly, to increase the quality and reliability of products.
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References
Shields, J. (1980). Adhesives: a reference book. Moscow: Mashinostroenie, 368.
Kovalchuk, L. M. (1987). Production of glued timber structures. Moscow: Forest industry, 248.
Krivenko, P., Petropavlovsky, О., Vozniuk, G. (2018). Alkaline Aluminosilicate Binder for Gluing Wood Board Materials. Key Engineering Materials, 761, 11–14. doi: http://doi.org/10.4028/www.scientific.net/kem.761.11
Guzii, S. G., Krivenko, P. V., Bondarenko, O. P., Kopylova, T. (2019). Study on Physico-Mechanical Properties of the Modified Alkaline Aluminosilicate Adhesive-Bonded Timber Elements. Solid State Phenomena, 296, 112–117. doi: http://doi.org/10.4028/www.scientific.net/ssp.296.112
Tsapko, Y., Zavialov, D., Bondarenko, O., Pinchevsʹka, O., Marchenco, N., Guzii, S. (2019). Design of fire-resistant heat- and soundproofing wood wool panels. Eastern-European Journal of Enterprise Technologies, 3 (10 (99)), 24–31. doi: http://doi.org/10.15587/1729-4061.2019.166375
Berzins, A., Morozovs, A., Gross, U., Iejavs, J. (2017) Mechanical properties of wood–geopolymer composite. Engineering for rural development, 16, 1167–1173. doi: http://doi.org/10.22616/erdev2017.16.n251
Bahrami, M., Shalbafan, A., Welling, J. (2019). Development of plywood using geopolymer as binder: effect of silica fume on the plywood and binder characteristics. European Journal of Wood and Wood Products, 77 (6), 981–994. doi: http://doi.org/10.1007/s00107-019-01462-3
Chen, T., Wu, Z., Niu, M., Xie, Y., Wang, X. (2015). Effect of Si–Al molar ratio on microstructure and mechanical properties of ultra-low density fiberboard. European Journal of Wood and Wood Products, 74 (2), 151–160. doi: http://doi.org/10.1007/s00107-015-0986-x
Chen, T., Xie, Y., Cai, L., Zhuang, B., Wang, X. A., Wu, Z. et. al. (2016). Mesoporous Aluminosilicate Material with Hierarchical Porosity for Ultralow Density Wood Fiber Composite (ULD_WFC). ACS Sustainable Chemistry & Engineering, 4 (7), 3888–3896. doi: http://doi.org/10.1021/acssuschemeng.6b00691
Guzii, S., Kryvenko, P., Guzii, O., Yushkevich, S. (2019). Determining the effect of the composition of an aluminosilicate binder on the rheotechnological properties of adhesives for wood. Eastern-European Journal of Enterprise Technologies, 6 (6 (102)), 30–38. doi: http://doi.org/10.15587/1729-4061.2019.185728
Guzii, S. G., Guzii, О. I., Yushkevich, S. V., Bazhelka, I. K. (2020). Study of the influence of organic and mineral modifiers on physical and rheological properties of aluminosilicate adhesives for gluing of wood. Bulletin of Odessa State Academy of Civil Engineering and Architecture, 79, 70–77. doi: http://doi.org/10.31650/2415-377x-2020-79-70-77
Glazacheva, E. N., Uspenskaya, M. V. (2015). Colloidal chemistry. Methodical instructions for laboratory work. Saint Petersburg: ITMO University, 62.
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